ATTENTION: The works hosted here are being migrated to a new repository that will consolidate resources, improve discoverability, and better show UTA's research impact on the global community. We will update authors as the migration progresses. Please see MavMatrix for more information.
Show simple item record
dc.contributor.author | Tong, Man-Yung Benjamin | en_US |
dc.date.accessioned | 2009-09-16T18:19:42Z | |
dc.date.available | 2009-09-16T18:19:42Z | |
dc.date.issued | 2009-09-16T18:19:42Z | |
dc.date.submitted | January 2009 | en_US |
dc.identifier.other | DISS-10360 | en_US |
dc.identifier.uri | http://hdl.handle.net/10106/1773 | |
dc.description.abstract | The focus of this thesis is on using state-of-the-art capillary electrophoresis (CE) in enantiomeric separations. Chapter 1 provides a brief introduction to enantiomeric separations using CE. Chapters 2 through 5 presents the use of different novel chiral selectors in CE. The selector properties and strategies for developing on enantiomeric separations are considered. Chapter 2 presents an overview on the most broadly useful chiral selectors for CE enantiomeric separations, sulfated cyclodextrins. Chapter 3 presents a new chiral selector, sodium arsenyl L-(+) tartrate. This chiral selector shows enantioselectivity for many amine-containing compounds and ruthenium (II) polypyridyl complexes and produces electropherograms with short to moderate migration times. Chapter 4 examines the CE enantiomeric separations of ten ruthenium (II) polypyridyl complexes using different types of cyclodextrin chiral selectors. Micellar capillary electrophoresis (MCE) was uilitized in this study. A comparison of the results using MCE to capillary zone electrophoresis (CZE) was discussed. Chapter 5 shows enantiomeric separations of almost 100 different amine-containing compounds using a new chiral selector, sulfated cyclofructan. Separations using the normal and reversed polarity mode were utilized in this study. Results from both separation modes were compared and discussed. | en_US |
dc.description.sponsorship | Armstrong, Daniel | en_US |
dc.language.iso | EN | en_US |
dc.publisher | Chemistry & Biochemistry | en_US |
dc.title | Studies Of Enantiomeric Separations Using Capillary Electrophoresis | en_US |
dc.type | M.S. | en_US |
dc.contributor.committeeChair | Armstrong, Daniel W. | en_US |
dc.degree.department | Chemistry & Biochemistry | en_US |
dc.degree.discipline | Chemistry & Biochemistry | en_US |
dc.degree.grantor | University of Texas at Arlington | en_US |
dc.degree.level | masters | en_US |
dc.degree.name | M.S. | en_US |
dc.identifier.externalLink | http://www.uta.edu/ra/real/editprofile.php?onlyview=1&pid=1017 | |
dc.identifier.externalLinkDescription | Link to Research Profiles | |
Files in this item
- Name:
- TONG_uta_2502M_10360.pdf
- Size:
- 2.019Mb
- Format:
- PDF
This item appears in the following Collection(s)
Show simple item record