Browsing Department of Chemistry and Biochemistry by Author "Dias, Rasika"
Now showing items 1-10 of 10
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3,5-Bis(3,5-bis(trifluoromethyl)phenyl)pyrazolyl complexes of Coinage Metals
Lakhi, Jaspreet Singh; 0000-0001-9167-0883 (2018-05-16)Pyrazoles are an important class of five membered heterocyclic compounds consisting of two nitrogen atoms. Pyrazolate anions serve as useful ligands in coordination chemistry. When fluorinated substituents are attached to ... -
COPPER(I) AND SILVER(I) COMPLEXES OF OLEFINS, ALKYNES, AND CYCLOPROPENES AND THEIR APPLICATIONS
Noonikara Poyil, Anurag; 0000-0002-6334-8421 (2022-05-17)Poly(pyrazolyl)borates are very popular ligands in organometallic chemistry due to their attractive properties. It is easy to modify the steric and electronic properties of these ligands by changing the pyrazolyl substituents. ... -
DIRECT FUNCTIONALIZATION OF INERT C-H AND C=C BONDS USING COPPER AND ZINC CATALYSTS SUPPORTED BY FLUORINATED LIGANDS, AND THE CHEMISTRY OF Fe(CO)5 AND ITS ANALOGS WITH COINAGE METAL IONS
Ponduru, Tharun Teja (2019-11-12)Transition-metal catalyzed direct functionalization of inert C-H and C=C bonds through nitrene- and oxo-transfer reactions are powerful and attractive synthetic strategies for constructing C-N and C-O bonds (e.g. found in ... -
HIGHLY FLUORINATED, COINAGE METAL COMPLEXES OF TRIS(PYRAZOLYL)BORATES WITH ADDITIONAL ELECTRON WITHDRAWING GROUPS AND PYRAZOLATE π-STACKINGS WITH ARENES
Jayaratna, Naleen Bandupriya (2016-05-11)Tris(pyrazolyl)borates are very popular ligands in inorganic chemistry, bioinorganic chemistry, and organometallic chemistry due to their attractive properties. It is possible to extensively modify the steric and electronic ... -
Modeling ETR1 with Isolable Coinage Metal Complexes Supported by Partially Fluorinated, and Methylated Scorpionates
Ridlen, Shawn Glen; 0000-0003-4564-3491Ethylene is a small molecule that functions as a plant hormone that is closely associated with several vital plant functions ranging from germination, shoot and root growth, sex expression, fruit ripening, senescence and ... -
Multinuclear copper(I) and silver(I) pyrazolates: synthesis, luminescence, and catalysis
Patterson, Monika R; 0000-0002-8794-8878 (2021-12-08)Copper and silver pyrazolate complexes have numerous fascinating properties such as luminescence, catalytic ability, and complexation with small molecules. Using both more widely studied non-fluorinated pyrazolates and ... -
N-HETEROCYCLIC CARBENE AND BIS(PYRAZOLYL)METHANE SUPPORTED COPPER(I) AND SILVER(I) COMPLEXES OF ORGANOTRIFLUOROBORATES
Zacharias, Adway Ouseph (2019-05-23)Organotrifluoroborates have gone from capturing the imagination of the scientific community to being used extensively in a host of applications ranging from being employed to study boron intermediates to being used as a ... -
Nickel (II) Pincer Complexes Supported By 2,6-Bis(3,5-ditolyl-2-pyrrolyl)Pyridine
Pramanik, AbhijitNi(II) pincer complexes are among the most important and useful compounds in homogeneous catalysis. Significant advancement has been made in this field in recent years. Many Ni(II) pincer complexes have been prepared and ... -
Scorpionate Supported And Unsupported Carbonyl And Ethylene Complexes Of Group 11 Metals
Fianchini, Mauro (Chemistry & Biochemistry, 2010-03-03)Carbon monoxide (CO) and small olefins represent perhaps the simplest, but most important ligand systems in coordination/organometallic chemistry. Simple carbonyl and ethylene compounds have started to appear in the field ... -
SYNTHESIS, STUDY, AND APPLICATIONS OF HIGHLY FLUORINATED COPPER PYRAZOLATE COMPLEXES OF SMALL ALKENE, ALKYNES AND CARBON MONOXIDE
Parasar, Devaborniny; 0000-0001-5739-2111 (2020-07-17)Trinuclear copper pyrazolate complexes (copper trimers) function as excellent precursors to synthesize multinuclear complexes of copper. Using highly fluorinated pyrazolates as supporting ligands, we have successfully ...