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Nanopore Stochastic Sensing With Ionic Liquid Supporting Electrolyte And Ionic Liquid Based Water Quantitation Using Gas Chromatography
(Chemistry & Biochemistry, 2011-03-03)
This dissertation focuses toward finding two new avenues to explore the properties of ionic liquids (ILs). First, ILs has been used as a novel, and advantageous supporting electrolytes in nanopore stochastic sensing ...
Enantiomeric Separation, Microorganism Studies And Determination Of Binding Constants Using Capillary Electrophoresis
(Chemistry & Biochemistry, 2010-03-03)
Enantiomeric separation of three series of compounds, including β-lactams, synthetic amino acids and ruthenium(II) polypyridyl complexes using different modes of capillary electrophoresis are discussed in this dissertation. ...
Application Of Pd-catalyzed Reactions In The Total Synthesis Of Oroidin-derived Alkaloids
(Chemistry & Biochemistry, 2014-03-17)
The oroidin family of marine natural products is a growing group of sponge-derived alkaloids which contain 2-aminoimidazole and pyrrolecarboxamide fragments as their signature features. Due to their structural diversity ...
Mixed Lineage Leukemia Histone Methylases In Hormonal Regulation Of HOX Genes And Their Disruption By Endocrine Disrupting Chemicals
(Chemistry & Biochemistry, 2014-03-10)
Homeobox (HOX) genes are highly conserved family of genes that play vital roles during cell differentiation and embryogenesis. Of the 39 HOX genes present in human, HOXC6 is a critical players in mammary gland development, ...
Total Synthesis Of Marine Derived Natural Products: Kealiiquinone And Ageliferin
(Chemistry & Biochemistry, 2014-03-17)
An intramolecular Diels-Alder reaction of vinylimidazoles has been developed and applied towards the total synthesis of benzimidazole and tetrahydrobenzimidazole natural products, namely kealiiquinone and ageliferin. A ...
Molecular Engineered Myoglobin With Unnatural Amino Acids As A Peroxidase
(Chemistry & Biochemistry, 2013-03-20)
Myoglobin (Mb) has been used as a model system to mimic other biologically important heme proteins like cytochrome P450 due to its ability to prepare mixed ligand complexes with different valencies, such as ferric, ferrous ...
A diffusionless transformation path relating Th₃P₄ and spinel structure opportunities to synthesize ceramic materials at high pressures
(Chemistry & Biochemistry, 2012-04-11)
Physical properties of solids at high pressure hold the key to many interesting questions in earth and planetary sciences, as well as in applied sciences. At high pressure, most ambient-pressure materials become unstable ...
Slowing DNA Translocation In A Biological Protein α-hemolysin Ion Channel
(Chemistry & Biochemistry, 2011-07-14)
During the past decade, nanopore DNA sequencing has emerged as a revolutionary prospect towards a "$1000 genome" goal set by U.S. National Institute of Health. In the nanopore approach, electrophoretic movement of ...
Mixed Lineage Luekemia Histone Methyltransferases In Hormonal Regulation Of HOXB9 And Target Gene Regulation
(Chemistry & Biochemistry, 2014-09-17)
Homeobox gene (HOX) genes are evolutionary conserved genes that play important roles in cell differentiation, cell proliferation and embryogenesis. HOX genes bind to the DNA via their homeodomain and act as transcription ...
Solid State Light Source Based Analytical Measurement Systems For Atmospheric Particles
(Chemistry & Biochemistry, 2012-04-11)
Solid-state light sources such as light-emitting diodes, use a solid semiconductor block instead of a conventional heated filament or discharge source. Such light sources are preferred in analytical instrumentation because ...