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APPLICATION OF NOVEL HETEROSUBSTITUTED VINYLIMIDAZOLES: AN APPROACH EN ROUTE TO THE TOTAL SYNTHESIS OF AXINELLAMINE A
(2016-05-11)
Our group is primarily interested in the total synthesis of oroidin-based pyrrole-imidazole-containing marine sponge-derived alkaloids. These pyrrole-imidazole natural products are a growing class of alkaloids with exotic ...
NEW STRATEGIES FOR CATALYTIC C-H AND OLEFIN HYDROSILYLATION
(2018-08-23)
In the works described here, new catalytic hydrosilylation strategies were explored. First, a highly selective, bond functionalization strategy, achieved via relay of two transition metal catalysts and use of traceless ...
SYNTHETIC AND MECHANISTIC INVESTIGATIONS OF RUTHENIUM ALKYLIDENE-CATALYZED ALKENE-SILANE CROSS-COUPLING REACTIONS
(2017-12-18)
Grubbs-type ruthenium alkylidene-catalyzed intramolecular alkene hydrosilylation and intermolecular dehydrogenative silylation and hydrosilylation of vinylarenes have been achieved with high regio- and stereoselectivity. ...