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SYNTHETIC AND MECHANISTIC INVESTIGATIONS OF RUTHENIUM ALKYLIDENE-CATALYZED ALKENE-SILANE CROSS-COUPLING REACTIONS
(2017-12-18)
Grubbs-type ruthenium alkylidene-catalyzed intramolecular alkene hydrosilylation and intermolecular dehydrogenative silylation and hydrosilylation of vinylarenes have been achieved with high regio- and stereoselectivity. ...