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Molecular Engineered Myoglobin With Unnatural Amino Acids As A Peroxidase
(Chemistry & Biochemistry, 2013-03-20)
Myoglobin (Mb) has been used as a model system to mimic other biologically important heme proteins like cytochrome P450 due to its ability to prepare mixed ligand complexes with different valencies, such as ferric, ferrous ...
A diffusionless transformation path relating Th₃P₄ and spinel structure opportunities to synthesize ceramic materials at high pressures
(Chemistry & Biochemistry, 2012-04-11)
Physical properties of solids at high pressure hold the key to many interesting questions in earth and planetary sciences, as well as in applied sciences. At high pressure, most ambient-pressure materials become unstable ...
Solid State Light Source Based Analytical Measurement Systems For Atmospheric Particles
(Chemistry & Biochemistry, 2012-04-11)
Solid-state light sources such as light-emitting diodes, use a solid semiconductor block instead of a conventional heated filament or discharge source. Such light sources are preferred in analytical instrumentation because ...
Capillary Electrophoresis Separation Of Neutral Organic Compounds, Pharmaceutical Drugs, Enantiomers And Anions
(Chemistry & Biochemistry, 2012-04-11)
The focus of this thesis is on using capillary electrophoresis (CE) with on-column UV detection in achiral and chiral separations. Chapter 1 provides a brief introduction to the principle, mechanism, meaning and application ...
Design And Synthesis Of A High Potential Ruthenium (II) Tetraazatetrapyridopentaphene Complex Capable Of Two-electron Reduction
(Chemistry & Biochemistry, 2010-03-03)
We report the synthesis of a complex, [(phen)₂Ru(tatpph)Ru(phen)₂]⁴⁺ (Ph⁴⁺), which like its predecessor compound, [(phen)₂Ru(tatppc)Ru(phen)₂]⁴⁺ (Pc ⁴⁺), can undergo two sequential 1-electron photoreductions in MeCN in ...
Ruthenium(II) Polypyridyl Complexes As Potential Anticancer Drugs: Synthesis, Characterization, Cell Permeability And Investigation Of Their Hypoxia-selectivity
(Chemistry & Biochemistry, 2013-03-20)
Research on biological activity of ruthenium polypyridyl complexes (RPCs) continues to attract interest as these complexes have shown promising anti-cancer activity both in vitro and in vivo. The mononuclear RPC, ...
Ruthenium(II) Polypyridyl Complexes As Potential Anticancer Drugs: Synthesis, Characterization, Cell Permeability And Localization
(Chemistry & Biochemistry, 2013-07-22)
Research on biological activities of ruthenium polypyridyl complexes (RPCs) continues to attract interest as these complexes have shown promising anticancer activity both in vitro and in vivo.¹⁻³ The mononuclear ...
Increasing Lipophilicity Of Redox Active Ruthenium Complexes As A Means To Enhance Cytotoxicity And Reduce Animal Toxicity
(Chemistry & Biochemistry, 2013-03-20)
The dinuclear and monomeric ruthenium(II) polypyridyl complexes [(phen)2Ru(tatpp)Ru(phen)2]Cl4 (P) and monomer [(phen)2Ru(tatpp)]Cl2 (MP) are promising candidates for anticancer drug development in terms of the observed ...
Ionization Competitors Extend The Linear Range Of Electrospray Ionization Mass Spectrometry
(Chemistry & Biochemistry, 2010-03-03)
ESI-MS has proven its applicability in quantitative analysis for a wide range of analytes. Its effectiveness relies on achieving sensitivity and linear range, although the latter is known to be limited. ESI-MS response ...
Analytical Characterization Of Anthocyanins From Natural Products By Reverse-phase Liquid Chromatography-photodiode Array-electrospray Ionization-ion Trap-time Of Flight Mass Spectrometry
(Chemistry & Biochemistry, 2011-03-03)
Anthocyanins are known to be one of the most powerful phytochemical antioxidant and believed to have a positive influence on a variety of health conditions. Numerous studies continue on these compounds that are readily ...