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COMBINING CHIRAL CHROMATOGRAPHIC STATIONARY PHASES AND N-DERIVATIZATION STRATEGIES FOR THE QUALITATIVE AND QUANTITATIVE ANALYSIS OF D-AMINO ACIDS, D-AMINO ACID CONTAINING PEPTIDES AND D-AMINO ACID RELATED SECONDARY METABOLITES USING LIQUID CHROMATOGRAPHY
(2023-05-12)
Amino acids are essential building blocks in all life on Earth. It was first mistakenly believed that only L-amino acids were of biological relevance in higher organisms, and D-amino acids were laboratory artifacts or ...
EPIMERIC PEPTIDES IN ALZHEIMER’S DISEASE: IMPLICATIONS FOR LIQUID CHROMATOGRAPHY-MASS SPECTROMETRY AND IMMUNOTHERAPIES
(2023-05-19)
Evidence has shown that the extracellular deposition of amyloid-beta (Aβ) peptide is a contributing factor of Alzheimer’s disease. Further, modifications to Aβ peptides may enhance the deposition of Aβ plaques and/or ...
Developing chemo-proteomics methods for tyrosine conjugation and studies of organometallic complexes of gold.
(2023-05-22)
**Please note that the full text is embargoed until 05/14/2025** ABSTRACT: The incredible changes in MS instrumentation since the late 1980s with the advent of electrospray ionization (ESI) and matrix-assisted laser ...
Nitroalkane Oxidase Inspired NO-Transfer Agents, NO Sensors, and the Computational Design of Fluorescent Sensors
(2023-03-13)
**Please note that the full text is embargoed until 2/25/2025** ABSTRACT: Flavin adenine dinucleotide and flavin mononucleotide are co-enzymes with biologically relevant redox potentials. They are involved in many chemical ...
ANALYSIS OF ISOTOPIC ISOMERS BY GAS CHROMATOGRAPHY AND MOLECULAR ROTATIONAL RESONANCE SPECTROSCOPY AND ENANTIOSELECTIVE METHOD DEVELOPMENT BY LIQUID CHROMATOGRAPHY
(2023-05-22)
**Please note that the full text is embargoed until 05/14/2024** ABSTRACT: This dissertation focuses on developing improved methods and a better understanding of gas and liquid chromatographic separation of isotopic isomers ...
TEMPERATURE-PRESSURE PHASE DIAGRAMS OF METAL NITROGEN COMPOUNDS THROUGH DENSITY FUNCTIONAL THEORY COMPUTATIONS AND THERMODYNAMIC CALCULATIONS
(2021-12-20)
The need for novel materials for new generations of applications is growing tremendously. One of many pathways to attain new materials is the route of high pressure synthesis. A particular active area in this high–pressure ...
Synthesis and Function of Ion-Selective Single-Molecule Fluorescent Imaging Molecules and Materials
(2022-05-18)
Neutrinos are fermion subatomic particles that interact only by weak subatomic forces—making them almost impossible to detect. However, they can be produced in specific radioactive decay reactions, such as beta decay.
We ...
SYNTHESIS OF ALLYLIC SYNTHONS AND APPLICATION OF PYRROLE THIOCARBOXYLIC ACIDS IN THE SYNTHESIS OF PYRROLE-IMIDAZOLE ALKALOIDS
(2022-05-17)
**Please note that the full text is embargoed until 5/16/2024** ABSTRACT: The first part of this dissertation describes the synthesis of allylic compounds from terminal alkenes without the use of any catalysts or oxidants. ...
SENSTIVE ENANTIOMERIC ANALYSIS OF N-ACYL HOMOSERINE LACTONES IN BACTERIAL MATRICES
(2023-01-03)
**Please note that the full text is embargoed until 12/13/2024** ABSTRACT: Communication between unicellular organism has long been studied with many facets yet to be discovered. A specific type of communication in ...
Computational materials chemistry: from polymer precursors to ceramics and high-pressure materials
(2022-08-17)
With advances in computing power, the field of computational chemistry has flourished. Using current computational resources, atomistic simulations of billion atoms and trillions of atoms have been performed. Computational ...